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By News Staff | March 24th 2009 12:00 AM | 2 comments | Print | E-mail | Track Comments

Two new greenhouse gases are accumulating in the atmosphere, according to an international research team led by scientists from the Scripps Institution of Oceanography in the US and CSIRO scientist, Dr Paul Fraser, from the Centre for Australian Weather and Climate Research.

Nitrogen trifluoride (NF3) and sulfuryl fluoride (SO2F2) are powerful greenhouse gases that have recently been discovered to be growing quickly in the global background atmosphere.

These gases are used in industrial processes, partly as alternatives to other harmful greenhouse and ozone depleting gases.

NF3 is used in the electronics industry – often as a replacement for perfluorocarbons (PFCs) – particularly in the manufacture of liquid-crystal flat-panel screens. SO2F2 is used as a replacement for methyl bromide, largely in structural fumigation applications. The new measurements of SO2F2 appear in a paper co-authored by Dr Fraser in the 12 March 2009 edition of the Journal of Geophysical Research.

"Information about the abundance of these gases in the atmosphere, their growth rates, lifetimes, and emissions is just emerging," Dr Fraser says.

"Currently the level of these gases in the atmosphere is low, but their concentration is growing. In addition, these gases have significant global-warming potential."

The first atmospheric observations of these gases from data collected around the world – particularly at Trinidad Head and La Jolla, California, and Cape Grim, Tasmania – will be presented at the GREENHOUSE 2009 conference.

"This research is likely to affect the revision of the Kyoto Protocol later this year," Dr Fraser says. "New emissions targets for the existing 'basket' of gases (carbon dioxide, methane, nitrous oxide, PFCs, hydrofluorocarbons, sulfur hexafluoride) are likely, as well as inclusion of the new greenhouse gases. A number of new signatories from the developed and developing world are also included in the revised Protocol."

The Centre for Australian Weather&Climate Research is a partnership between CSIRO and the Bureau of Meteorology.



Comments

rholley's picture
Ironic that methyl bromide was banned according to the Montreal Protocol because of its effect on the ozone layer, only to be replaced by a potent greenhouse gas.  But if someone had taken a look at the infrared spectra of nitrogen trifluoride and sulfuryl fluoride before their widespread use, then they could have sung along recently with Carrie Underwood and Randy Travis on American Idol:

I told you so!


Unfortunately this is a familiar story to those conversant with current debates within the Montreal Protocol process, particularly in respect of the much more ubiquitous HCFC and HFC refrigerant substitutes for CFCs in refrigeration and air conditioning.

Despite the feasibility of natural refrigerants including ammonia, carbon dioxide and hydrocarbons, proponents of HFCs were able to dominate in the refrigerants debate since the late 1980s, and only in recent years are natural refrigerants beginning to achieve significant market penetration in some sectors. Increasing the price of HFCs by either taxes or inclusion in Emissions Trading Schemes will assist in reducing emissions, but international cooperation to set phase out objectives for all high GWP gases is clearly required.

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