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New Bacteria-Resistant Films Are Only 50 Billionths Of A Meter Thick

Chemistry

MIT engineers have created ultrathin films made of polymers that could be applied to medical devices and other surfaces to control microbe accumulation. The inexpensive, easy-to-produce films could provide a valuable layer of protection for the health care industry by helping to reduce the spread of hospital-acquired infections, which take the lives of 100,000 people and cost the United States an estimated $4.5 billion annually.

The researchers found they could control the extent of bacterial adhesion to surfaces by manipulating the mechanical stiffness of polymer films called polyelectrolyte multilayers. Thus, the films could be designed to prevent accumulation of hazardous bacteria or promote growth of desirable bacteria.

“All other factors being equal, mechanical stiffness of material surfaces increases bacterial adhesion,” said Krystyn Van Vliet, the Thomas Lord Assistant Professor of Materials Science and Engineering.

Conducting Polymers - Get Ready For Plastic Nerves

Chemistry

A type of plastic that exhibits metallic and semi-conductor-like properties will be described in an inaugural doctoral lecture at the University of Leicester on Wednesday June 4th(*).

In his lecture, Dr. M. A. Mohamoud will discuss a novel class of materials called “conducting polymers.” Conducting polymers are smart materials that can mimic biological systems and can be used as components of artificial nerves, electronic noses/tongues, drug-release-and-delivering systems, and artificial muscles.

They can also be used as energy storage devices in battery technology, electrochromic display devices (in smart window technology and light emitting diodes), and biological sensor technology.

Practical Science - Measuring Chili Hotness With Nanotubes

Chemistry

Nano-whatever is all the rage. They're a big deal because they can make a blacker version of black and lots of other things but what does that even mean?

Richard Compton and his team at Oxford University are here to help make carbon nanotubes understandable to everyone - namely, by making it relevant to food. They have developed a sensitivity technique to measure the levels of capsaicinoids, the substances that make chilis hot, in samples of hot sauce. They report their findings in The Analyst.

The current industry procedure is to use a panel of taste-testers, which is highly subjective. Compton’s new method unambiguously determines the precise amount of capsaicinoids and is not only quicker and cheaper than taste-testers but more reliable for purposes of food standards; tests could be rapidly carried out on the production line.

How Do Chemicals That Keep Fruit Fresh Work?

Chemistry

Ethylene (C2H4) is a gaseous hormone produced naturally in plants and by man in combustion (1). When plants encounter ethylene they soften and ripen (fruit) or wilt and fade (flowers.)

We all like fruit that is ripe but lasts longer and flowers that stay colorful are a good thing so some growers spray plants with products like EthylBloc for flowers or SmartFresh for fruits and vegetables which contain a compound, 1-methylcyclopropane or 1-MCP, that blocks ethylene’s action on plants.

But how this compound works at the molecular level remains uncertain despite several chemical pathways chemists have proposed.

New Fatty Acids Discovered - But For Mechanical Engineering

Chemistry

CSIRO researchers have discovered a new class of fatty acids -- alpha-hydroxy polyacetylenic fatty acids -- that they say could be used as sensors for detecting changes in temperature and mechanical stress loads.

CSIRO Entomology business manager, Cameron Begley, said researchers believed the discovery opened up an entirely new class of chemistry. “Some of these alpha-hydroxy polyacetylenic fatty acids act as indicators for a range of different conditions, such as mechanical stress or heat, and display self-assembling properties. Others display anti-microbial properties,” he said.

GNA: DNA's Chemical Cousin Is A Nanotechnology Building Block

Chemistry

In the rapid and fast-growing world of nanotechnology, researchers are continually on the lookout for new building blocks to push innovation and discovery to scales much smaller than the tiniest speck of dust.

In the Biodesign Institute at Arizona State University, researchers are using DNA to make intricate nano-sized objects. Working at this scale holds great potential for advancing medical and electronic applications. DNA, often thought of as the molecule of life, is an ideal building block for nanotechnology because they self-assemble, snapping together into shapes based on natural chemical rules of attraction. This is a major advantage for Biodesign researchers like Hao Yan, who rely on the unique chemical and physical properties of DNA to make their complex nanostructures.

Researchers Engineer World's Best Moisture Barrier For OLEDs, 1000X Better Than Current Methods

Chemistry

A breakthrough barrier technology from Singapore A*STAR’s Institute of Materials Research and Engineering (IMRE) protects sensitive devices like organic light emitting diodes (OLEDs) and solar cells from moisture 1000 times more effectively than any other technology available in the market, opening up new opportunities for the up-and-coming plastic electronics sector.

A team of scientists from Singapore’s Institute of Materials Research and Engineering (IMRE) has developed a new patented film that has the highest reported water vapour barrier performance to date, as tested by the UK Centre for Process Innovation.

The tests have shown that the new film is 1,000 times more impervious to moisture than existing technologies. This means a longer lifetime for plastic electronic devices such as solar cells and flexible displays that use these high-end films but whose sensitive organic materials are easily degraded by water vapour and oxygen.

Electropositive Alloy Makes A Great Shark Repellant For Fishing Gear

Chemistry

A recent study by NOAA scientists and colleagues on captive juvenile sandbar sharks showed the presence of an electropositive alloy, in this case palladium neodymium, clearly altered the swimming patterns of individual animals and temporarily deterred feeding in groups of sharks.

Rare earth metals have previously been reported to deter spiny dogfish from attacking bait due to interactions with the shark’s electroreceptive system, which detects weak electric fields including those generated by their prey.

Electric fields generated by electropositive alloys are believed to deter or repel sharks by overloading their sensory systems, a behavior that may help fishery biologists develop a strategy to reduce the bycatch of sharks in longline gear. Shark bycatch is an increasing priority worldwide given diminished populations of many shark species, and because sharks compete with target species for baited lines, reducing fishing efficiency and increasing operating costs.

Self-Healing Ceramics Protect Against Radiation

Chemistry

Researchers at the Department of Energy's Pacific Northwest National Laboratory found that the restless movement of oxygen atoms heals radiation-induced damage in the engineered ceramic yttria-stabilized zirconia.

This may lead to development of radiation-resistant materials for nuclear power plants and waste storage.

Scientists Ram Devanathan and Bill Weber modeled how well that ceramic and other materials stand up to radiation. "If you want a material to withstand radiation over millennia, you can't expect it to just sit there and take it. There must be a mechanism for self-healing," said Devanathan.

New Hybrid Gel Is A Biodegradable Sensor

Chemistry

Your contact lenses of the future could be completely biodegradable. A soft contact lens is a hydrogel - a solid, gelatinous mass consisting of water incorporated in a polymer network.

Now Berkeley researchers have developed a technique for the formation of hybrid materials from synthetic polymers and proteins, fusing the biological functions of proteins with the processing properties of plastics.

Aaron P. Esser-Kahn and Matthew B. Francis say they have successfully synthesized a green-fluorescing biodegradable gel that responds to changes in pH value and temperature. These polymer-protein hybrid materials can also be used in sensors, nanomachine parts, or drug-delivery systems.

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